How much coding and web design experience do you have? Dreamweaver is a tool -- a very good one. But it's only as good (or bad) as the person using it. The more skills you bring to the table (knowledge of HTML, CSS, PHP, JavaScript and Web Design Theory), the better your results will be.
Start with these links & bookmark them:
- http://www.html.net/
- http://w3schools.com/
- http://www.csstutorial.net/
- http://phrogz.net/css/HowToDevelopWithCSS.html
- http://webdesign.tutsplus.com/sessions/web-design-theory/
After you have learned the fundamentals, work through this 5-part tutorial:
- Creating your first web site in DW CC-
https://helpx.adobe.com/dreamweaver/learn/tutorials/how-to/first-website-part1.html
Nancy O.